Jesse James: Sandra Bullock 'Takes My Breath Away'

Although they may not be the traditional Hollywood couple, Jesse James and Sandra Bullock are a match and Jesse enjoyed donning a suit and being his wife's date at the Oscars on Sunday.

"It's awesome," he told PEOPLE of being her date as they made their way into the Governor's Ball at the Hollywood & Highland Grand Ballroom after the Oscar ceremony Sunday. "It's a once-in-a-lifetime opportunity to support my wife and her work. She does it all the time for me. She goes to Mexico, to the desert, to the hospital – a lot – to support me and my work. The least I can do is put on a suit and support her."

"She's beautiful. She's amazing. She takes my breath away,” James said. "Sometimes I look at her and I do, I just lose my breath."